Sedimentary & surface deposits
At the Earth's surface, rivers, waves, weathering and the Sun do the concentrating. They sort heavy grains from light ones, dissolve away everything but the metal, and boil off water to leave salts behind.
- Explain how moving water sorts gold, tin and heavy mineral sands into placers by density and grain size
- Link banded iron formations to the oxygenation of the planet
- Describe residual deposits: bauxite, nickel laterite and rare-earth clays made by weathering
- Explain how supergene enrichment can raise the grade of a copper deposit three times or more
- Describe evaporites and lithium brines, and sediment-hosted copper
- Use the mineral-systems approach, thinking about the whole system, at every scale
Placers: sorting by density
When rock weathers and erodes, its minerals end up as grains in rivers and on beaches. Moving water carries grains along, but how far depends on size and density. Most sand is quartz, at about 2.65 g/cm³. Gold is about 19 g/cm³, seven times denser. Wherever the current slows, the heavy grains drop out first and the light ones are carried on. Repeat that over thousands of years and you get a placer: a concentration of heavy, durable minerals in sediment. Panning for gold is the same process done by hand.
A placer mineral needs two properties: it must be dense, and it must survive weathering and abrasion. Gold, cassiterite (tin oxide), diamond, garnet, zircon, ilmenite and rutile (titanium oxides) and monazite (a rare-earth and thorium phosphate) all qualify.
Size matters as well as density. How fast a grain sinks depends on both, so a large, light grain can sink as fast as a small, heavy one. A quartz grain about half a millimetre across settles at roughly the same speed as a gold flake a tenth of a millimetre across, so the two end up side by side. Grains that settle at the same speed are called hydraulically equivalent. It is why fine "flour" gold can travel a long way down a river, while coarse nuggets stay close to their source.
Grains of quartz, ilmenite and gold of different sizes are dropped in at the surface of a river 0.5 m deep. Each sinks at its own settling speed while the current sweeps it downstream. Speed up the current and watch which grains stay in this 10 m stretch and which are carried on.
Settling speeds use a standard formula for natural sand grains in water (Ferguson and Church, 2004). The model is simplified: each grain falls through steady, even flow and stops where it first touches the bed. Real rivers are turbulent, and grains already on the bed can be picked up again, so the sorting is messier. The vertical scale is stretched.
Heavy mineral sands
Waves sort sand along the coasts of Kerala (Chavara), Tamil Nadu and Odisha (Chhatrapur), leaving black bands rich in ilmenite, rutile, zircon, garnet and monazite. India's rare earths have come mainly from monazite in these sands.
Gold, tin and diamond placers
Most of the great gold rushes, in California, Victoria and the Klondike, began in river placers. Southeast Asia's tin belt and many of the world's diamonds, including India's historic Golconda stones from the Krishna valley, came from river gravels.
Witwatersrand
Gold-bearing conglomerates nearly 3 billion years old, usually interpreted as palaeoplacers (fossil placers) later modified by hot fluids. The single largest source of gold in history, roughly a third or more of all gold ever mined. They also contain rounded grains of pyrite and uraninite, minerals that would not survive in rivers today, a clue that the air then had almost no oxygen.
Banded iron formations
Most of the world's iron ore comes from banded iron formations (BIFs): rocks of alternating thin layers of iron oxide and chert (fine-grained silica). The biggest formed between about 2.5 and 1.8 billion years ago, but many are older, some as old as 3.8 billion years. The chemistry is simple. Iron dissolves easily in water that has no oxygen, as ferrous iron (Fe²⁺). The early oceans had almost no oxygen, so they held a lot of dissolved iron. When photosynthesising microbes began releasing oxygen, it reacted with that iron to make ferric iron (Fe³⁺), which is insoluble. At first this happened only locally, in sunlit shallow water where the microbes lived, before oxygen built up in the air. The ocean, in effect, rusted, and the rust settled on the seafloor. Iron formations kept forming before and during the Great Oxidation Event covered in A brief history of Earth.
- Iron in. Hot springs on the deep seafloor add dissolved ferrous iron (Fe²⁺). With no oxygen in the deep water, it stays dissolved.
- Upwelling. Currents carry the iron-rich deep water up onto shallow shelves.
- Oxygen. In the sunlit surface water, photosynthesising microbes release oxygen.
- Rust rain. Iron meets oxygen and becomes insoluble ferric iron, which settles as fine rust.
- Bands. Iron-rich layers alternate with silica (chert) layers, building a banded iron formation.
A typical BIF contains roughly 30% iron. The richest ores, at 60% iron or more, formed where later fluids or deep weathering dissolved the silica away and left the iron behind, the same residual logic as the next section. The Hamersley Basin in the Pilbara of Western Australia is the world's largest iron-ore province. India's iron ore comes from BIFs too: the Odisha–Jharkhand belt around Noamundi and Joda–Barbil, Bailadila in Chhattisgarh, Bellary–Hospet in Karnataka, and Goa. Most of India's iron formations are Archaean, older than 2.6 billion years, so they formed well before oxygen built up in the air.
Residual deposits: what weathering leaves behind
In Weathering, erosion & soil you saw that chemical weathering dissolves the soluble parts of a rock and carries them away in water. In a hot, wet tropical climate, over millions of years, this goes to an extreme. Calcium, magnesium, sodium, potassium and eventually even silica are leached out. What is left is a residual deposit, enriched in whatever was least soluble. The thick, red, iron- and aluminium-rich weathering profile that results is a laterite, from the Latin for "brick", a word coined in Kerala in 1807 for the material cut into building blocks there. Below the laterite lies saprolite: rock so rotted that you can dig it with a spade, yet still showing its original structure.
On ultramafic rock such as peridotite, the same weathering makes a nickel laterite. Olivine dissolves, magnesium and silica leave, iron stays at the top, and nickel does something in between: it dissolves near the surface, moves down with the water and is captured again lower in the profile, where the chemistry changes.
Run tropical weathering on peridotite (about 0.25% nickel) for up to 10 million years and watch where the nickel ends up.
An illustrative model with round, typical numbers, not data from one deposit. The profile thickens as the weathering front eats downwards, at very roughly 5–10 m per million years at first, then more slowly; erosion of the surface is ignored. It is the same reaction that enhanced rock weathering speeds up in a field, run here for millions of years.
Bauxite
Almost all aluminium comes from bauxite, a laterite rich in aluminium hydroxides. India's largest deposits cap the plateaus of the Eastern Ghats in Odisha and Andhra Pradesh; Panchpatmali near Koraput is one of Asia's largest bauxite mines. Smaller deposits sit on the Deccan basalts.
Nickel laterite
Ultramafic rocks such as peridotite hold only about 0.2–0.3% nickel, locked in olivine. Tropical weathering dissolves the olivine and concentrates the nickel, plus cobalt, to around 1–2%. Indonesia, built largely on such laterites, now mines well over half the world's nickel (around 60%); New Caledonia and the Philippines are other big sources.
Ion-adsorption clays
In southern China, deeply weathered granites hold rare-earth ions loosely stuck to the surfaces of clay grains. Washing the clay with a salt solution releases them. These modest-grade deposits are the main global source of the heavy rare earths, such as dysprosium, used in high-performance magnets.
Supergene enrichment: weathering upgrades copper
When a copper deposit is uplifted and exposed, weathering attacks it from the top down. Rain and oxygen react with pyrite (iron sulphide) to make sulphuric acid. The acid dissolves copper from the upper part of the deposit and carries it downward. When the solution reaches the water table, the level below which the ground is saturated and oxygen is scarce, conditions flip and copper re-precipitates, often as chalcocite (Cu2S) replacing the original sulphides. Copper from a thick leached zone is packed into a thinner layer below. This is supergene enrichment ("supergene" means formed by water from above).
If the land is uplifted or the climate dries, the water table drops. The old blanket is now above it, so it is leached in turn, and its copper moves down to a new blanket. Each drop adds the copper of the old blanket to the new one, which is why the richest blankets formed where the water table fell in stages.
A schematic profile with a simple copper budget: the leached cap keeps about 0.05% Cu, the oxide zone about 0.3%, and the rest of the copper above the water table moves into the blanket. The iron-oxide gossan at the surface is a classic prospector's clue to buried sulphides. Many great Chilean porphyries, including Chuquicamata and Escondida, were first mined profitably for their supergene blankets.
Evaporites and brines
When water evaporates, the salts dissolved in it stay behind, and the water left becomes saltier. In a basin with no outlet to the sea and a dry climate, this can go on until minerals crystallise out in a predictable order: first carbonates and gypsum, then halite (rock salt), and finally the most soluble potassium and magnesium salts. The resulting rocks are evaporites. Ancient evaporite beds are the world's source of potash (potassium salts for fertiliser), as in Saskatchewan in Canada.
Thresholds are approximate textbook values for seawater. Layer thicknesses are roughly in proportion (halite is about three-quarters of all the salt) except that the thinnest layers are drawn thicker so you can see them. Evaporating a 1,000 m column of seawater leaves only about 15 m of salt, which is why thick evaporites need a basin that is refilled again and again.
Lithium is so soluble that it rarely crystallises at all. Instead it builds up in the leftover brine in the porous sediments beneath a salt flat (a salar). In the high Andes, in the "lithium triangle" of Chile, Argentina and Bolivia, volcanic rocks and hot springs supply lithium, and intense sunshine and wind evaporate the water. The best brines, such as those beneath the Salar de Atacama, hold more than a thousand milligrams of lithium per litre, thousands of times more than seawater. Producers pump the brine into shallow ponds and let the Sun concentrate it further over many months.
Sediment-hosted copper is a cousin of these systems. Oxidised, salty basin water can carry copper (and cobalt) a long way. When it soaks into a layer rich in organic matter or sulphide, such as a black shale, the chemistry switches from oxidising to reducing and copper sulphides precipitate along that layer for tens of kilometres. The Central African Copperbelt of Zambia and the Democratic Republic of the Congo is the outstanding example, and the reason the DRC mines most of the world's cobalt. The Kupferschiefer ("copper shale") of Poland and Germany is another.
- Oxidised brine. Salty water in red sandstone carries copper as chloride complexes; the iron oxide that colours the rock red shows the water holds oxygen.
- Reducing layer. A thin black shale full of organic matter and pyrite consumes oxygen.
- Redox front. Where brine meets shale the chemistry flips, and copper (with cobalt) precipitates as sulphides in a thin layer that can run for kilometres.
- Salt source. Evaporite beds dissolve into the basin water and make it salty enough to carry copper.
The mineral-systems approach
Across these four modules a pattern has emerged. Every deposit, magmatic, hydrothermal or surface, is the end product of a mineral system: a source of metal, an energy source and fluid to move it, a pathway, a trap, and luck with preservation afterwards. This way of thinking, developed largely by Australian geoscientists from the 1990s onwards, has changed how exploration is done.
- SourceWhere could the metal, the fluid and the energy have come from?
- PathwayWhat faults, permeable layers or conduits could have focused the flow?
- TrapWhere did the chemistry or physics change abruptly, so metal dropped out?
- PreservationHas the deposit survived erosion since, or been buried or eroded away?
The point is that each ingredient leaves its own evidence at a different scale, and you can look for it before you have seen any ore at all.
- Continent: which belts had the right tectonic setting? For porphyry copper: ancient and modern subduction arcs.
- Region: which parts of the belt had fertile magmas and major structures? Intrusions of the right age and chemistry along big arc-parallel faults.
- District: where is there evidence that fluids actually flowed? Alteration halos, gossans, geochemical and magnetic anomalies.
- Deposit: where exactly is the trap? Zoning vectors towards the potassic core; drill targets.
Instead of searching for "something that looks like a known mine", explorers map the probability of each ingredient being present and look where they overlap. How that is done in practice, with mapping, geochemistry, remote sensing and drilling, is the subject of Prospecting & the exploration pipeline, and the physics of seeing underground is covered in Geophysical methods.
Weathering and sedimentary processes make some of the world's most important ores. Bauxite supplies nearly all of its aluminium, and nickel laterites a growing share of its nickel, so exploring for them means understanding exactly the soil chemistry described above.
Enhanced rock weathering speeds up exactly the reactions that build laterites, bauxites and supergene ores. When basalt weathers in a farm field, its calcium and magnesium dissolve and leave in water, carrying captured carbon with them as bicarbonate (see Weathering, erosion & soil). Over millions of years in the tropics, the same leaching leaves behind the iron and aluminium that become laterite and bauxite.
India's tropical soils include true laterites, so understanding this end-member is useful in the field: a lateritic soil has already lost most of its reactive minerals and behaves very differently from a young soil on fresh rock. The chemistry of carbon removal and the chemistry of these ores are the same chemistry, run at different speeds.