Sedimentary & surface deposits

At the Earth's surface, rivers, waves, weathering and the Sun do the concentrating. They sort heavy grains from light ones, dissolve away everything but the metal, and boil off water to leave salts behind.

By the end of this module, you will be able to
  • Explain how moving water sorts gold, tin and heavy mineral sands into placers by density and grain size
  • Link banded iron formations to the oxygenation of the planet
  • Describe residual deposits: bauxite, nickel laterite and rare-earth clays made by weathering
  • Explain how supergene enrichment can raise the grade of a copper deposit three times or more
  • Describe evaporites and lithium brines, and sediment-hosted copper
  • Use the mineral-systems approach, thinking about the whole system, at every scale

Placers: sorting by density

When rock weathers and erodes, its minerals end up as grains in rivers and on beaches. Moving water carries grains along, but how far depends on size and density. Most sand is quartz, at about 2.65 g/cm³. Gold is about 19 g/cm³, seven times denser. Wherever the current slows, the heavy grains drop out first and the light ones are carried on. Repeat that over thousands of years and you get a placer: a concentration of heavy, durable minerals in sediment. Panning for gold is the same process done by hand.

A placer mineral needs two properties: it must be dense, and it must survive weathering and abrasion. Gold, cassiterite (tin oxide), diamond, garnet, zircon, ilmenite and rutile (titanium oxides) and monazite (a rare-earth and thorium phosphate) all qualify.

Size matters as well as density. How fast a grain sinks depends on both, so a large, light grain can sink as fast as a small, heavy one. A quartz grain about half a millimetre across settles at roughly the same speed as a gold flake a tenth of a millimetre across, so the two end up side by side. Grains that settle at the same speed are called hydraulically equivalent. It is why fine "flour" gold can travel a long way down a river, while coarse nuggets stay close to their source.

Density (g/cm³) 0 5 10 15 20 Quartz 2.65 Diamond 3.5 Garnet ~4 Rutile 4.2 Ilmenite 4.7 Zircon 4.7 Monazite 5.2 Cassiterite 7 Gold 19.3 · ~7× quartz Plan view of a meandering river Point bar Cut bank Cut bank Point bar
Gold grainsPoint-bar sandEroding cut bankRiver; dashes show the fastest flow
Left: the density contrast that makes placers work. Ilmenite and rutile are titanium ores, zircon is a zirconium ore, monazite carries rare earths and thorium, and cassiterite is the main tin ore. Right: in a river, heavy grains collect where flow slows, such as on point bars inside bends, while the fast water on the outside of each bend erodes a cut bank. Gold also collects behind bedrock ridges and in cracks at the base of the gravel. Density is not the whole story: a small heavy grain can travel as far as a large light one.
Try it · a sorting flume

Grains of quartz, ilmenite and gold of different sizes are dropped in at the surface of a river 0.5 m deep. Each sinks at its own settling speed while the current sweeps it downstream. Speed up the current and watch which grains stay in this 10 m stretch and which are carried on.

Side view of a 10 metre stretch of river 0.5 metres deep, vertical scale exaggerated. Grains of quartz, ilmenite and gold of different sizes are released at the water surface at the upstream end. Each grain sinks while the current carries it downstream, so it follows a straight sloping path to the bed. Heavy and coarse grains land close to the start; light and fine grains travel further or are carried out of the reach entirely. carried on current → 0 2 4 6 8 10 m distance downstream from where the grains start
QuartzIlmeniteGoldbigger dot = bigger grain

Settling speeds use a standard formula for natural sand grains in water (Ferguson and Church, 2004). The model is simplified: each grain falls through steady, even flow and stops where it first touches the bed. Real rivers are turbulent, and grains already on the bed can be picked up again, so the sorting is messier. The vertical scale is stretched.

India · beaches

Heavy mineral sands

Waves sort sand along the coasts of Kerala (Chavara), Tamil Nadu and Odisha (Chhatrapur), leaving black bands rich in ilmenite, rutile, zircon, garnet and monazite. India's rare earths have come mainly from monazite in these sands.

TiZrREETh
Rivers

Gold, tin and diamond placers

Most of the great gold rushes, in California, Victoria and the Klondike, began in river placers. Southeast Asia's tin belt and many of the world's diamonds, including India's historic Golconda stones from the Krishna valley, came from river gravels.

AuSnDiamond
South Africa · ancient

Witwatersrand

Gold-bearing conglomerates nearly 3 billion years old, usually interpreted as palaeoplacers (fossil placers) later modified by hot fluids. The single largest source of gold in history, roughly a third or more of all gold ever mined. They also contain rounded grains of pyrite and uraninite, minerals that would not survive in rivers today, a clue that the air then had almost no oxygen.

AuU

Banded iron formations

Most of the world's iron ore comes from banded iron formations (BIFs): rocks of alternating thin layers of iron oxide and chert (fine-grained silica). The biggest formed between about 2.5 and 1.8 billion years ago, but many are older, some as old as 3.8 billion years. The chemistry is simple. Iron dissolves easily in water that has no oxygen, as ferrous iron (Fe²⁺). The early oceans had almost no oxygen, so they held a lot of dissolved iron. When photosynthesising microbes began releasing oxygen, it reacted with that iron to make ferric iron (Fe³⁺), which is insoluble. At first this happened only locally, in sunlit shallow water where the microbes lived, before oxygen built up in the air. The ocean, in effect, rusted, and the rust settled on the seafloor. Iron formations kept forming before and during the Great Oxidation Event covered in A brief history of Earth.

oxygen-free below this line sunlit surface water banded iron formation:iron oxide and chert layers 12345 An ocean about 2.5 billion years ago
  1. Iron in. Hot springs on the deep seafloor add dissolved ferrous iron (Fe²⁺). With no oxygen in the deep water, it stays dissolved.
  2. Upwelling. Currents carry the iron-rich deep water up onto shallow shelves.
  3. Oxygen. In the sunlit surface water, photosynthesising microbes release oxygen.
  4. Rust rain. Iron meets oxygen and becomes insoluble ferric iron, which settles as fine rust.
  5. Bands. Iron-rich layers alternate with silica (chert) layers, building a banded iron formation.
How the ocean rusted. Iron that was dissolved in oxygen-free deep water fell out as rust wherever it met oxygen made by microbes. Why the iron and silica layers alternate, perhaps with seasons or pulses of iron supply, is still debated.

A typical BIF contains roughly 30% iron. The richest ores, at 60% iron or more, formed where later fluids or deep weathering dissolved the silica away and left the iron behind, the same residual logic as the next section. The Hamersley Basin in the Pilbara of Western Australia is the world's largest iron-ore province. India's iron ore comes from BIFs too: the Odisha–Jharkhand belt around Noamundi and Joda–Barbil, Bailadila in Chhattisgarh, Bellary–Hospet in Karnataka, and Goa. Most of India's iron formations are Archaean, older than 2.6 billion years, so they formed well before oxygen built up in the air.

Residual deposits: what weathering leaves behind

In Weathering, erosion & soil you saw that chemical weathering dissolves the soluble parts of a rock and carries them away in water. In a hot, wet tropical climate, over millions of years, this goes to an extreme. Calcium, magnesium, sodium, potassium and eventually even silica are leached out. What is left is a residual deposit, enriched in whatever was least soluble. The thick, red, iron- and aluminium-rich weathering profile that results is a laterite, from the Latin for "brick", a word coined in Kerala in 1807 for the material cut into building blocks there. Below the laterite lies saprolite: rock so rotted that you can dig it with a spade, yet still showing its original structure.

BauxiteAl oxides, hydroxides Clay zonekaolinite (Al silicate) Saproliterotten rock Fresh rockbasalt or khondalite 0 10 m 20 m 30 m Bauxite (aluminium) Chemistry, % of rock 0% 20% 40% 60% Al₂O₃ stays SiO₂ leached
A bauxite profile, roughly to scale. Water percolating downwards (blue arrow) carries away silica, calcium, magnesium, sodium and potassium; aluminium is almost insoluble, so it stays and is concentrated in the bauxite at the top. Bauxite can form on basalt or, in the Eastern Ghats, on khondalite, an aluminium-rich metamorphic rock with garnet and sillimanite. Values are typical, not from one deposit.

On ultramafic rock such as peridotite, the same weathering makes a nickel laterite. Olivine dissolves, magnesium and silica leave, iron stays at the top, and nickel does something in between: it dissolves near the surface, moves down with the water and is captured again lower in the profile, where the chemistry changes.

Try it · grow a nickel laterite

Run tropical weathering on peridotite (about 0.25% nickel) for up to 10 million years and watch where the nickel ends up.

A weathering profile developing on peridotite over millions of years, with two plots beside it. As time passes the profile thickens; magnesium oxide is leached from the upper part; iron oxide is left behind and concentrates at the top; nickel moves down and builds a peak in the saprolite at several times the fresh-rock grade.

An illustrative model with round, typical numbers, not data from one deposit. The profile thickens as the weathering front eats downwards, at very roughly 5–10 m per million years at first, then more slowly; erosion of the surface is ignored. It is the same reaction that enhanced rock weathering speeds up in a field, run here for millions of years.

Aluminium · India

Bauxite

Almost all aluminium comes from bauxite, a laterite rich in aluminium hydroxides. India's largest deposits cap the plateaus of the Eastern Ghats in Odisha and Andhra Pradesh; Panchpatmali near Koraput is one of Asia's largest bauxite mines. Smaller deposits sit on the Deccan basalts.

AlGa
Nickel · Indonesia

Nickel laterite

Ultramafic rocks such as peridotite hold only about 0.2–0.3% nickel, locked in olivine. Tropical weathering dissolves the olivine and concentrates the nickel, plus cobalt, to around 1–2%. Indonesia, built largely on such laterites, now mines well over half the world's nickel (around 60%); New Caledonia and the Philippines are other big sources.

NiCoSc
Rare earths · China

Ion-adsorption clays

In southern China, deeply weathered granites hold rare-earth ions loosely stuck to the surfaces of clay grains. Washing the clay with a salt solution releases them. These modest-grade deposits are the main global source of the heavy rare earths, such as dysprosium, used in high-performance magnets.

REEDyTb

Supergene enrichment: weathering upgrades copper

When a copper deposit is uplifted and exposed, weathering attacks it from the top down. Rain and oxygen react with pyrite (iron sulphide) to make sulphuric acid. The acid dissolves copper from the upper part of the deposit and carries it downward. When the solution reaches the water table, the level below which the ground is saturated and oxygen is scarce, conditions flip and copper re-precipitates, often as chalcocite (Cu2S) replacing the original sulphides. Copper from a thick leached zone is packed into a thinner layer below. This is supergene enrichment ("supergene" means formed by water from above).

If the land is uplifted or the climate dries, the water table drops. The old blanket is now above it, so it is leached in turn, and its copper moves down to a new blanket. Each drop adds the copper of the old blanket to the new one, which is why the richest blankets formed where the water table fell in stages.

Try it · lower the water table
Vertical weathering profile through a copper deposit, with a plot of copper grade against depth beside it. From the top: a leached cap or gossan with almost no copper, an oxide zone with malachite and chrysocolla, the water table, a supergene enrichment blanket with the highest grade, and primary sulphide ore below at about 0.5 percent copper. Buttons lower the water table in steps; each time, the old blanket is leached and its copper is carried down into a new, thicker and richer blanket.

A schematic profile with a simple copper budget: the leached cap keeps about 0.05% Cu, the oxide zone about 0.3%, and the rest of the copper above the water table moves into the blanket. The iron-oxide gossan at the surface is a classic prospector's clue to buried sulphides. Many great Chilean porphyries, including Chuquicamata and Escondida, were first mined profitably for their supergene blankets.

Evaporites and brines

When water evaporates, the salts dissolved in it stay behind, and the water left becomes saltier. In a basin with no outlet to the sea and a dry climate, this can go on until minerals crystallise out in a predictable order: first carbonates and gypsum, then halite (rock salt), and finally the most soluble potassium and magnesium salts. The resulting rocks are evaporites. Ancient evaporite beds are the world's source of potash (potassium salts for fertiliser), as in Saskatchewan in Canada.

Try it · evaporate seawater
Left: a basin of seawater whose level falls as water evaporates, with salt layers building on its floor. Right: four minerals in the order they crystallise, each with a bar showing how much of it has come out of the water: carbonate from about 50 percent evaporated, gypsum from about 80 percent, halite from about 90 percent, and potassium and magnesium salts above about 97 percent.

Thresholds are approximate textbook values for seawater. Layer thicknesses are roughly in proportion (halite is about three-quarters of all the salt) except that the thinnest layers are drawn thicker so you can see them. Evaporating a 1,000 m column of seawater leaves only about 15 m of salt, which is why thick evaporites need a basin that is refilled again and again.

Lithium is so soluble that it rarely crystallises at all. Instead it builds up in the leftover brine in the porous sediments beneath a salt flat (a salar). In the high Andes, in the "lithium triangle" of Chile, Argentina and Bolivia, volcanic rocks and hot springs supply lithium, and intense sunshine and wind evaporate the water. The best brines, such as those beneath the Salar de Atacama, hold more than a thousand milligrams of lithium per litre, thousands of times more than seawater. Producers pump the brine into shallow ponds and let the Sun concentrate it further over many months.

Rain and snowmelt leachsalts from volcanic rock Evaporation removes water;salts stay behind salt crust brine pumpedto ponds Brine (Li, K) in porous sedimentsaltiest towards the centre volcanic bedrockno outlet to the sea groundwater
A salar in a closed basin. Water flows in but can only leave by evaporation, so dissolved lithium, potassium, sodium and boron build up year after year. The concentration step is the same as boiling down a pan of seawater, done by the Sun over tens of thousands of years or more. Producers then repeat it in a chain of ponds, each brine more concentrated than the last.

Sediment-hosted copper is a cousin of these systems. Oxidised, salty basin water can carry copper (and cobalt) a long way. When it soaks into a layer rich in organic matter or sulphide, such as a black shale, the chemistry switches from oxidising to reducing and copper sulphides precipitate along that layer for tens of kilometres. The Central African Copperbelt of Zambia and the Democratic Republic of the Congo is the outstanding example, and the reason the DRC mines most of the world's cobalt. The Kupferschiefer ("copper shale") of Poland and Germany is another.

Limestone and evaporites black shale Red-bed sandstoneoxidised brine carrying Cu basement 1234
  1. Oxidised brine. Salty water in red sandstone carries copper as chloride complexes; the iron oxide that colours the rock red shows the water holds oxygen.
  2. Reducing layer. A thin black shale full of organic matter and pyrite consumes oxygen.
  3. Redox front. Where brine meets shale the chemistry flips, and copper (with cobalt) precipitates as sulphides in a thin layer that can run for kilometres.
  4. Salt source. Evaporite beds dissolve into the basin water and make it salty enough to carry copper.
A sediment-hosted copper deposit, not to scale: the ore layer is typically metres thick but kilometres long. It is the same "chemistry flips" trap as the supergene blanket, with the redox boundary set by a rock layer instead of the water table.

The mineral-systems approach

Across these four modules a pattern has emerged. Every deposit, magmatic, hydrothermal or surface, is the end product of a mineral system: a source of metal, an energy source and fluid to move it, a pathway, a trap, and luck with preservation afterwards. This way of thinking, developed largely by Australian geoscientists from the 1990s onwards, has changed how exploration is done.

  1. SourceWhere could the metal, the fluid and the energy have come from?
  2. PathwayWhat faults, permeable layers or conduits could have focused the flow?
  3. TrapWhere did the chemistry or physics change abruptly, so metal dropped out?
  4. PreservationHas the deposit survived erosion since, or been buried or eroded away?

The point is that each ingredient leaves its own evidence at a different scale, and you can look for it before you have seen any ore at all.

1Continent 1,000s of km 2Region 100s of km 3District 10s of km 4Deposit 1 km or less
  1. Continent: which belts had the right tectonic setting? For porphyry copper: ancient and modern subduction arcs.
  2. Region: which parts of the belt had fertile magmas and major structures? Intrusions of the right age and chemistry along big arc-parallel faults.
  3. District: where is there evidence that fluids actually flowed? Alteration halos, gossans, geochemical and magnetic anomalies.
  4. Deposit: where exactly is the trap? Zoning vectors towards the potassic core; drill targets.
Searching for porphyry copper at four nested scales. Each frame zooms into the box in the one before; each scale asks a different question and uses different evidence.

Instead of searching for "something that looks like a known mine", explorers map the probability of each ingredient being present and look where they overlap. How that is done in practice, with mapping, geochemistry, remote sensing and drilling, is the subject of Prospecting & the exploration pipeline, and the physics of seeing underground is covered in Geophysical methods.

Look for the system, not the deposit. Deposits are small; the footprints of the systems that made them are big.
Why this matters at Alt Earth

Weathering and sedimentary processes make some of the world's most important ores. Bauxite supplies nearly all of its aluminium, and nickel laterites a growing share of its nickel, so exploring for them means understanding exactly the soil chemistry described above.

Enhanced rock weathering speeds up exactly the reactions that build laterites, bauxites and supergene ores. When basalt weathers in a farm field, its calcium and magnesium dissolve and leave in water, carrying captured carbon with them as bicarbonate (see Weathering, erosion & soil). Over millions of years in the tropics, the same leaching leaves behind the iron and aluminium that become laterite and bauxite.

India's tropical soils include true laterites, so understanding this end-member is useful in the field: a lateritic soil has already lost most of its reactive minerals and behaves very differently from a young soil on fresh rock. The chemistry of carbon removal and the chemistry of these ores are the same chemistry, run at different speeds.